THE RELATIONSHIP BETWEEN ACOUSTIC FEATURES OF SECOND LANGUAGE SPEECH AND LISTENER EVALUATION OF SPEECH QUALITY

Second language (L2) speech is typically less fluent than native speech, and differs from it phonetically. While the speech of some L2 English speakers seems to be easily understood by native listeners despite the presence of a foreign accent, other L2 speech seems to be more demanding, such that listeners must expend considerable effort in order to understand it. One reason for this increased difficulty may simply be the speaker’s pronunciation accuracy or phonetic intelligibility. If a L2 speaker’s pronunciations of English sounds differ sufficiently from the sounds that native listeners expect, these differences may force native listeners to work much harder to understand the divergent speech patterns. However, L2 speakers also tend to differ from native ones in terms of fluency – the degree to which a speaker is able to produce appropriately structured phrases without unnecessary pauses, self-corrections or restarts. Previous studies have shown that measures of fluency are strongly predictive of listeners’ subjective ratings of the acceptability of L2 speech: Less fluent speech is consistently considered less acceptable (Ginther, Dimova, & Yang, 2010). However, since less fluent speakers tend also to have less accurate pronunciations, it is unclear whether or how these factors might interact to influence the amount of effort listeners exert to understand L2 speech, nor is it clear how listening effort might relate to perceived quality or acceptability of speech. In this dissertation, two experiments were designed to investigate these questions

Synthesis and characterization of nanostructured and noble metal-based chalcogenide semiconductors

Màster en Nanociència i Nanotecnologia, Facultat de Física, Universitat de Barcelona, Curs: 2017-2018. Tutor: Albert FiguerolaPlatinum containing chalcogenides seem to have bright potential due to the special electrical and catalytic properties stemming from platinum combined with the semiconductor ones of chalcogenides. In this work, a set of synthesis were designed in order to know the influence of different reaction parameters such as temperature, amount of reactants and also different kinds of capping agents on the growth or formation of such nanostructures. The characterization results suggest that a ternary nanostructured chalcogenide system containing two noble metals (Platinum and Silver) was successfully synthesised by using OlAm as capping agent at 120ºC by means of cation exchange reactions. Furthermore, the composition of this ternary is assumed to be Ag3PtSe2. As described through this work, the variation on the previously mentioned reaction parameters allows modifying the morphology and composition of this ternary system. Additionally, the possibility of synthesizing nanostructured binary platinum selenide has also been explore

Proceedings of the 9th PLA Symposium

This is the combined conference proceedings of the 9th annual Purdue Linguistics Association (PLA) Symposium

Electronic Structures of Graphene Layers on Metal Foil: Effect of Point Defects

Here we report a facile method to generate a high density of point defects in graphene on metal foil and show how the point defects affect the electronic structures of graphene layers. Our scanning tunneling microscopy (STM) measurements, complemented by first principle calculations, reveal that the point defects result in both the intervalley and intravalley scattering of graphene. The Fermi velocity is reduced in the vicinity area of the defect due to the enhanced scattering. Additionally, our analysis further points out that periodic point defects can tailor the electronic properties of graphene by introducing a significant bandgap, which opens an avenue towards all-graphene electronics.Comment: 4 figure

Strain Induced One-Dimensional Landau-Level Quantization in Corrugated Graphene

Theoretical research has predicted that ripples of graphene generates effective gauge field on its low energy electronic structure and could lead to zero-energy flat bands, which are the analog of Landau levels in real magnetic fields. Here we demonstrate, using a combination of scanning tunneling microscopy and tight-binding approximation, that the zero-energy Landau levels with vanishing Fermi velocities will form when the effective pseudomagnetic flux per ripple is larger than the flux quantum. Our analysis indicates that the effective gauge field of the ripples results in zero-energy flat bands in one direction but not in another. The Fermi velocities in the perpendicular direction of the ripples are not renormalized at all. The condition to generate the ripples is also discussed according to classical thin-film elasticity theory.Comment: 4 figures, Phys. Rev.

Facile morphology control of gold(0) structures from aurophilic assemblies

Different gold microstructures have been synthesized by using supramolecular gold(I) organometallic compounds as templates and Ag nanoparticles as reducing agent. The use of fibers resulting from supramolecular assemblies of neutral gold(I) compounds, gives rise to the formation of microrods. The use of supramolecular assemblies from ionic molecules results in spherical or square-based prisms gold microstructures, depending on the shape of the supramolecular gold(I) precursor assembly. In addition to temperature and reaction time, the solvent has a strong influence on the formation and morphology of the gold structures. Well-defined star-like morphologies have been obtained in chloroform

Monitoring the insertion of Pt into Cu2−xSe nanocrystals: a combined structural and chemical approach for the analysis of new ternary phases

The tuning of the chemical composition in nanostructures is a key aspect to control for the preparation of new multifunctional and highly performing materials. The modification of Cu2−xSe nanocrystals with Pt could provide a good way to tune both optical and catalytic properties of the structure. Although the heterogeneous nucleation of metallic Pt domains on semiconductor chalcogenides has been frequently reported, the insertion of Pt into chalcogenide materials has not been conceived so far. In this work we have explored the experimental conditions to facilitate and enhance the insertion of Pt into the Cu2−xSe nanocrystalline lattice, forming novel ternary phases that show a high degree of miscibility and compositional variability. Our results show that Pt is mainly found as a pure metal or a CuPt alloy at high Pt loads (Pt : Cu atomic ratio in reaction medium >1). However, two main ternary CuPtSe phases with cubic and monoclinic symmetry can be identified when working at lower Pt : Cu atomic ratios. Their structure and chemical composition have been studied by local STEM-EDS and HRTEM analyses. The samples containing ternary domains have been loaded on graphite-like C3N4 (g-C3N4) semiconductor layers, and the resulting nanocomposite materials have been tested as promising photocatalysts for the production of H2 from aqueous ethanolic solutions

Angle-dependent van Hove singularities and their breakdown in twisted graphene bilayers

The creation of van der Waals heterostructures based on a graphene monolayer and other two-dimensional crystals has attracted great interest because atomic registry of the two-dimensional crystals can modify the electronic spectra and properties of graphene. Twisted graphene bilayer can be viewed as a special van der Waals structure composed of two mutual misoriented graphene layers, where the sublayer graphene not only plays the role of a substrate, but also acts as an equivalent role as the top graphene layer in the structure. Here we report the electronic spectra of slightly twisted graphene bilayers studied by scanning tunneling microscopy and spectroscopy. Our experiment demonstrates that twist-induced van Hove singularities are ubiquitously present for rotation angles theta less than about 3.5o, corresponding to moir\'e-pattern periods D longer than 4 nm. However, they totally vanish for theta > 5.5o (D < 2.5 nm). Such a behavior indicates that the continuum models, which capture moir\'e-pattern periodicity more accurately at small rotation angles, are no longer applicable at large rotation angles.Comment: 5 figure

Spontaneous Hetero-attachment of Single-Component Colloidal Precursors for the Synthesis of Asymmetric Au-Ag2X (X = S, Se) Heterodimers

Finding simple, easily controlled, and flexible synthetic routes for the preparation of ternary and hybrid nanostructured semiconductors is always highly desirable, especially to fulfill the requirements for mass production to enable application to many fields such as optoelectronics, thermoelectricity, and catalysis. Moreover, understanding the underlying reaction mechanisms is equally important, offering a starting point for its extrapolation from one system to another. In this work, we developed a new and more straightforward colloidal synthetic way to form hybrid Au-Ag2X (X = S, Se) nanoparticles under mild conditions through the reaction of Au and Ag2X nanostructured precursors in solution. At the solid-solid interface between metallic domains and the binary chalcogenide domains, a small fraction of a ternary AuAg3X2phase was observed to have grown as a consequence of a solid-state electrochemical reaction, as confirmed by computational studies. Thus, the formation of stable ternary phases drives the selective hetero-attachment of Au and Ag2X nanoparticles in solution, consolidates the interface between their domains, and stabilizes the whole hybrid Au-Ag2X systems